EFFECTS OF AL2O3 NANOPARTICLES ON THE PHYSICAL AND THERMAL PROPERTIES OF TRANSESTERIFIED SENNATORA OIL

Authors

  • AUWALU, I. A. Aliko Dangote University of Science and Technology Author
  • YARO, I. G. Maitama Sule University Kano image/svg+xml Author
  • MUHAMMAD, A. Aliko Dangote University of Science and Technology Author
  • ALIYU, S. A. Rabiu Musa Kwankwaso College of Advanced and Remedial Studies Author

DOI:

https://doi.org/10.5281/zenodo.20573618

Keywords:

Global Warming, Nanoparticles, Renewable Energy, Sennatora oil, Transesterification

Abstract

This study investigated the effects of Al2O3 nanoparticles on the physical and thermal properties of trans-esterified Sennatora oil, aiming to enhance its combustion efficiency. The study also evaluates the oil’s physical and thermal properties, both with and without the addition of Al2O3 nanoparticles. The methods adopted in the study include extraction of oil from Sennatora seeds obtained from Kano, Northwest Nigeria, its purification and the synthesis of trans-esterified Sennatora oil, and its characterization using Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). The composition of free fatty acids (FFAs) was investigated using Gas chromatography Mass Spectroscopy (GCMS). The results showed an acid value of 3.74mgKOH/g and pH of 5.8 for the crude oil and 0.45mgKOH/g and pH of 6.5 for the esterified oil. The addition of Al2O3 nanoparticles has increased pH to 6.9 while the flash point of the oil was observed to have decreased from 2250C to 2180C while the calorific value increased from 17.68MJ/kg to 19.45MJ/g. The major fatty acids contained oleic acid (30.73%), linoleic acid (23.41%), stearic acid (6.52%), and palmitic acid (11.54%). This work underscores the importance of exploring alternative bio-resources like Sennatora to address global energy and environmental challenges effectively.

Downloads

Download data is not yet available.

References

Abishek, M. S., Kachhap, S., Rajak, U., Verma, T. N., Singh, T. S., Shaik, S., Cuce, E., and Alwetaishi, M. (2024). Alumina and titanium nanoparticles to diesel–Guizotia abyssinica (L.) biodiesel blends on MFVCR engine performance and emissions. Sustainable Energy Technologies and Assessments, 61. https://doi.org/10.1016/J.SETA.2023.103580

Abubakar, H., Hammari, A. M., Abubakar, A., and Maiwada, A. (2021). Biodiesel Production from Cassia tora Seed Oil Through Acid-Base Catalysed Method. Journal of Biochemistry, Microbiology and Biotechnology, 9(1), 25–29.

Alam, R., Rahman Imon, R., Enamul, M., Talukder, K., Akhter, S., Hossain, M. A., Ahammad, F., and Rahman, M. M. (2021). GC-MS analysis of phytoconstituents from Ruellia prostrata and Senna tora and identification of potential anti-viral activity against SARS-CoV-2. Pubs.Rsc.Org. https://doi.org/10.1039/d1ra06842c

Atadashi, I. M., Aroua, M. K., Aziz, A. R. A., and Sulaiman, N. M. N. (2013a). The effects of catalysts in biodiesel production: A review. Journal of Industrial and Engineering Chemistry, 19(1), 14–26.

Atadashi, I. M., Aroua, M. K., Aziz, A. R. A., and Sulaiman, N. M. N. (2013b). The effects of catalysts in biodiesel production: A review. Journal of Industrial and Engineering Chemistry, 19(1), 14–26.

Baskar, G., Kalavathy, G., Aiswarya, R., and Abarnaebenezer Selvakumari, I. (2018). Advances in bio-oil extraction from nonedible oil seeds and algal biomass. Advances in Eco-Fuels for a Sustainable Environment, 187–210. https://doi.org/10.1016/B978-0-08-102728-8.00007-3

El-Araby, R. (2024). Biofuel production: exploring renewable energy solutions for a greener future. In Biotechnology for Biofuels and Bioproducts (Vol. 17, Number 1). BioMed Central Ltd. https://doi.org/10.1186/s13068-024-02571-9

Gebremariam, S. N., and Marchetti, J. M. (2017). Biodiesel production technologies. AIMS Energy, 5(3), 425–457. https://doi.org/10.3934/energy.2017.3.425

Gomes, P., Weng, Z., Tao, Y., Fei, H., Deng, W., Chen, Y., Zhao, Z., Liang, X., and Nie, Y. (2023). Green Production of Biodiesel from High Acid Value Oil via Glycerol Esterification and Transesterification Catalyzed by Nano Hydrated Eggshell-Derived CaO. https://doi.org/10.3390/en16186717

Harsh Gupta, B., and Anand Santosh Kumar Rai, G. (2021). Study of rheological and tribological properties of metal oxide nanoparticles blended lubricating oil.

Interlenghi, S. F., de Medeiros, J. L., and Fernandes Araújo, O. de Q. (2023). Fatty acid methyl ester and fatty acid ethyl ester inventories and sustainability indicators. Sustainability of Methylic and Ethylic Biodiesel Production Routes, 73–122. https://doi.org/10.1016/B978-0-443-21942-9.00010-8

Jamo, H. U., Ismail, U. I., Yunusa, K., Durimin Iya, S. G., Tolufase, E., Bello, O. M., and Getso, I. Y. (2023). Influence of Egg Shell As Heterogeneous Catalyst on the Viscosity of Transesterified Jatropha Oil. Science World Journal, 18(1), 2023.

Kayed, H., Abdel Aziz, M. M., and Gad, M. S. (2024). Enriching various biodiesel feedstocks with Al2O3 nanoparticles in diesel engines: Performance, emissions, and exergy analysis. Propulsion and Power Research, 13(4), 553–569. https://doi.org/10.1016/J.JPPR.2024.11.001

Lin, C. Y., and Wu, X. E. (2022). Determination of Cetane Number from Fatty Acid Compositions and Structures of Biodiesel. Processes, 10(8). https://doi.org/10.3390/pr10081502

Morakinyo, S. O., Aroke, U. O., Mohammed, J., Muhammad, I. M., and Yusuf, A. A. (2021). Characterization of Cassia Tora Seed (CTS) Oil-Based Biodiesel-Diesel Blends. 7(1). https://doi.org/10.22178/pos.66-3

Nura, I., Jamo, H. U., Getso, I. Y., Tolufase, E., Belo, O. M., Ismail, U. I., Musa, F. U., and Yusuf, A. (2023). The effect of addition of fly ash on physical properties of transetererified calabash oil as source of biodiesel. Science World Journal, 18(1), 55–59.

Raman Ibrahim, N. B. B., Puchooa, D., Govinden-Soulange, J., and Facknath, S. (2021). Cassia species: a potential source of biopesticides. Journal of Plant Diseases and Protection, 128(2), 339–351. https://doi.org/10.1007/S41348-020-00408-9

Saravanan, S., and Dubey, R. S. (2020). Synthesis of SiO2 nanoparticles by sol-gel method and their optical and structural properties. Rom. J. Inf. Sci. Technol, 23(1), 105–112.

Singh, Y., Abd Rahim, E., Singh, N. K., Sharma, A., Singla, A., and Palamanit, A. (2022). Friction and wear characteristics of chemically modified mahua (madhuca indica) oil-based lubricant with SiO2 nanoparticles as additives. Wear, 508, 204463.

Tomar, M., sources, N. K.-E., Recovery, part A., utilization, undefined, and 2020, undefined. (2019). Influence of nanoadditives on the performance and emission characteristics of a CI engine fuelled with diesel, biodiesel, and blends–a review. Taylor and FrancisM Tomar, N KumarEnergy Sources, Part A: Recovery, Utilization, and Environmental Effects, 2020•Taylor and Francis, 42(23), 2944–2961. https://doi.org/10.1080/15567036.2019.1623347

Zibaee, E., Javadi, B., Sobhani, Z., Akaberi, M., Farhadi, F., Amiri, M. S., Baharara, H., Sahebkar, A., and Emami, S. A. (2023). Cassia species: A review of traditional uses, phytochemistry and pharmacology. Pharmacological Research - Modern Chinese Medicine, 9, 100325. https://doi.org/10.1016/J.PRMCM.2023.100325

Downloads

Published

2026-06-06

How to Cite

AUWALU, I. A., YARO, I. G., MUHAMMAD, A., & ALIYU, S. A. (2026). EFFECTS OF AL2O3 NANOPARTICLES ON THE PHYSICAL AND THERMAL PROPERTIES OF TRANSESTERIFIED SENNATORA OIL. International Journal of Renewable Energy and Environment, 4(2), 166-177. https://doi.org/10.5281/zenodo.20573618

Similar Articles

11-20 of 31

You may also start an advanced similarity search for this article.